Nippon Yakin Kogyo NAS254N Corrosion Resistant Alloys

Manufacturer: Nippon Yakin Kogyo Co., Ltd
Model: NAS254N

NAS254N (UNS S32053)
High Corrosion Resistant Super Stainless Steel

NAS254N (SUS836L, UNS S32053) is a high corrosion resistance austenitic stainless steel with a high nickel, high chromium, high molybdenum alloy design, and provides excellent corrosion resistance in severe corrosion environments such as high temperature seawater. Depending on the environment, this stainless steel offers high economy combined with corrosion resistance comparable to that of Nickel alloy and pure titanium. Nippon Yakin supplies this product in plate, sheet, and strip form.

Chemical Composition 23Cr-25Ni-5.5Mo-0.2N
Product shape

Coil

Sheet

Plate

Workability Hot and cold workability similar to standard austenitic stainless steels like Type 304, 316; requires care due to high strength
Weldability Various methods applicable; shielded metal arc welding, TIG welding, and plasma welding suitable. Alloy 276 consumables recommended.
Machinability Machining is difficult but easier than Ni-based alloys; use of ultra-hard tool and slow feed rate recommended
Heat Treatment Solution annealing at 1080-1180°C, quenching in water or rapid cooling
Pickling Mixture of nitric acid and hydrofluoric acid; material should be immersed in alkaline solution before pickling, shot blasting effective
Applications Food manufacturing, Salt manufacturing, Pharmaceutical plants, Chemical plants, Marine structures, Heat exchangers

Steel Grade/Standard

Nippon Yakin Grade JIS G 4304/4305 ASTM A240 EN
NAS254N SUS836L UNS S32053

Chemical Composition

Specification C Si Mn P S Ni Cr Mo N
SUS836L ≤0.030 ≤1.00 ≤2.00 ≤0.045 ≤0.030 24.00 – 26.00 19.00 – 24.00 5.00 – 7.00 ≤0.25
UNS S32053 ≤0.030 ≤1.00 ≤1.00 ≤0.030 ≤0.010 24.00 – 26.00 22.00 – 24.00 5.00 – 6.00 0.17 – 0.22
Physical Properties
Density [g/cm³] 8.06
Specific heat [J/kg·K] 457
Electrical resistivity [µΩ·cm] 94.7
Thermal conductivity [W/m·K] 11.9
Average coefficient of thermal expansion [10⁻⁶/°C] 30-100°C: 14.6
30-200°C: 15.2
30-300°C: 15.5
30-400°C: 15.8
Young’s modulus [MPa] 19.7 × 10⁴
Magnetism None
Melting range [°C] 1330 – 1390

Mechanical Properties

Mechanical Properties at Room Temperature

Specification 0.2% proof stress [MPa] Tensile strength [MPa] Elongation [%] Hardness [HBW] Hardness [HRBW] Hardness [HV]
SUS836L ≥275 ≥640 ≥40 ≤217 ≤96 ≤230
UNS S32053 ≥295 ≥640 ≥40 ≤217 ≤96
Cold-rolled sheet 2mm 385 760 46
Hot-rolled plate 16mm 336 725 56 172
Corrosion Resistance

NAS254N is a high Cr, high Mo stainless steel which provides excellent pitting corrosion resistance and crevice corrosion resistance in high Cl environments. As a high Ni steel, it also offers excellent stress corrosion cracking resistance.

Pitting Corrosion Resistance

Alloy ASTM G48 Method A ASTM G48 Method C
22°C 50°C Critical pitting corrosion temperature CPT (°C)
NAS255 × 50
NAS329J3L × 50
NAS64 55
NAS254N 80

ASTM G48 Method A (○: No pitting corrosion, ×: Pitting corrosion)
Test solution: 6%FeCl3
Test temperature: 22°C, 50°C (Recommended temperature in this test)
Test time: 72h

Crevice Corrosion Resistance

Alloy ASTM G48 Method D
Critical crevice corrosion temperature CCT (°C)
NAS255 10
NAS329J3L 25
NAS64 30
NAS254N 45

* Test conditions: ASTM G48 Method D
* Test solution: 6%FeCl3 + 1%HCl
* Test time: 72h

Stress Corrosion Cracking Resistance

Alloy MgCl₂ concentration (boiling point °C are in brackets)
45% (155°C) 42% (143°C) 40% (138°C) 38% (134°C) 35% (126°C) 30% (115°C) 25% (110°C) 20% (108°C)
NAS255 × × × ×
NAS329J3L × × × × ×
NAS64 × ×
NAS254N

 Test conditions: Immersion in boiling MgCl₂ solution
They use a U-bend test specimen.
○: No stress corrosion cracking
×: Stress corrosion cracking

Acid Resistance

Corrosion rate in sulfuric acid at 80°C (mm/y)

Alloy 5% 10% 20% 40% 60% 80%
NAS255 <0.01 <0.01 0.78 2.95 0.48 5.01
NAS329J3L 0.01 0.17 4.65 365.9 145.6 106.4
NAS64 <0.01 0.02 1.07 191.9 1054 60.72
NAS254N 0.02 0.05 1.02 2.11 2.16 7.76

Test time: 24h

Corrosion rate in hydrochloric acid at 80°C (mm/y)

Alloy 0.1% 1% 2% 3%
NAS255 <0.01 0.01 2.70 3.72
NAS329J3L 0.02 0.03 31.10 60.62
NAS64 0.01 0.12 12.94 30.51
NAS254N 0.01 0.02 0.01 9.14

Test time: 24h

Reference

Alloy JIS UNS No. Chemical composition
NAS255 SUS890L N08904 20Cr-24Ni-4.3Mo-1.5Cu
NAS329J3L SUS329J3L S32205 22Cr-5.3Ni-3.0Mo-0.16N
NAS64 SUS329J4L S32605 25Cr-6.5Ni-3.3Mo-0.17N
NAS254N SUS836L S32053 23Cr-25Ni-5.5Mo-0.2N

Workability

The hot and cold workability of NAS254N is basically the same as that of standard austenitic stainless steels such as Type 304, Type 316, etc. The fact that this is a high-strength material requires consideration in both cold and hot working.

Weldability

Various welding methods are applicable in the same manner as with the standard austenitic stainless steels, including shielded metal arc welding, TIG welding, and plasma welding. Alloy 276 welding consumable should be used.

Machinability

As a feature of high Ni stainless steels, although machining is difficult in comparison with the standard austenitic stainless steels, it is easier than with Ni-based alloys. A ultrahard tool should be used in machining if at all possible. It is also advisable to use a slower feed rate and deeper cutting depth.

Heat Treatment

Solution annealing of NAS254N should be performed at the temperature range from 1130 to 1180°C followed by being quenched in water or rapidly cooled by other means. (Conditions provided in ASTM A480/A480M)

Pickling

A mixture of nitric acid and hydrofluoric acid is used in pickling. However, due to the high corrosion resistance of NAS254N, scale is somewhat difficult to remove in comparison with Type 304. Therefore, the material should be immersed in an alkaline solution before pickling or, if possible, shot blasting is extremely effective.

Applications

Food manufacturing plants, Salt manufacturing plants, Pharmaceutical plants, Chemical plants, Flue gas desulfurization plants, Marine structures, Marine equipment, related equipment, Heat exchangers, Various types of bleaching equipment.

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